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| supramolecular chemistry: Supramolecular Chemistry Peter J. Cragg, 2010-08-26 The aim of this book is to return to the biomimicry and medicinal potential that inspired many of the early supramolecular chemists and to set it in the context of current advances in the field. Following an overview of supramolecular chemistry, the first section considers the efforts made to synthesize artificial systems that mimic biological entities. The second section addresses the application of supramolecular principles to molecular diagnostics with a particular emphasis on the ‘receptor-relayreporter’ motif. Many of the examples chosen have clinical importance. The third section takes the clinical diagnostic theme further and demonstrates the therapeutic applications of supramolecular chemistry through photodynamic therapy, drug delivery, and the potential for synthetic peptides to form antibiotic tubes. The short epilogue considers the potential for supramolecular solutions to be found for further challenges in biomimetic and therapeutic chemistry. |
| supramolecular chemistry: Supramolecular Chemistry Stefan Kubik, 2024-07-22 This introductory textbook on supramolecular chemistry is a thoroughly revised and expanded version of the 1st edition, originally published in 2020. All chapters have been brought up to date and now include Further Reading sections that highlight relevant developments. In addition, a new chapter on supramolecular polymers has been added. With these changes, this book provides an even more comprehensive introduction to the exciting field of supramolecular chemistry than before. Readers will learn what forces hold supramolecular architectures together, how supramolecular systems are created and characterized, how molecular switches, motors, transporters, catalysts, chemosensors, and other functional systems work, and where supramolecular chemistry can play or already plays a role in our lives. In 2022 the first edition of this book won the Literature Prize of the German Chemical Industry Association VCI. For the full press release (in German): https://www.vci.de/fonds/presse-und-infos/pressemitteilungen/preisgeld-fuer-supramolekuele.jsp |
| supramolecular chemistry: Supramolecular Chemistry - Fundamentals and Applications Katsuhiko Ariga, Toyoki Kunitake, 2006-08-02 The fundamentals of supramolecular chemistry to the latest developments on the subject are covered by this book. It sets out to explain the topic in a relatively easy way. The basic concepts of molecular recognition chemistry are included. Molecules with fascinating shapes and functions such as fullerenes, carbon nanotubes, dendrimers, rotaxane, and catenane, and molecular assemblies are also explained. Thereafter applications of supermolecules to nanotechnology are introduced with many examples of molecular devices. The last part of the book describes biological supermolecules and their mimics. Though simply explained undergraduate and graduate students in Chemistry will be able to use aspects of this work as an advanced textbook. |
| supramolecular chemistry: Supramolecular Chemistry Fritz V?gtle, 1993-07-20 Supramolecular Chemistry F. Vögtle, Institut für Organische Chemie und Biochemie der Universität Bonn, Germany This book consists of twelve self-contained chapters on supramolecular structures. Using numerous examples of ‘aggregates’, the chemistry involved is described from different angles. Here, the multidisciplinary aspect of this domain of chemistry becomes apparent, as the close relationships with physics, physical chemistry, materials science and biochemistry are emphasized. The book begins with simple complex-forming compounds and ends with complex ‘supramolecules’ and ‘suprastructures’. One of the practicalities of this volume is the inclusion of many stereoscopic views of supramolecular structures, most of them based on X-ray crystallography. |
| supramolecular chemistry: Applications of Supramolecular Chemistry Hans-Jörg Schneider, 2012-03-28 Applications of Supramolecular Chemistry introduces the use of non-covalent interactions and molecular recognition for many fields. Applications include the analysis of technically, medically, and environmentally important chemical compounds, their separation, purification and removal, and the design of new materials, including supramolecular elect |
| supramolecular chemistry: Core Concepts in Supramolecular Chemistry and Nanochemistry Jonathan W. Steed, David R. Turner, Karl Wallace, 2007-04-30 Supramolecular chemistry and nanochemistry are two strongly interrelated cutting edge frontiers in research in the chemical sciences. The results of recent work in the area are now an increasing part of modern degree courses and hugely important to researchers. Core Concepts in Supramolecular Chemistry and Nanochemistry clearly outlines the fundamentals that underlie supramolecular chemistry and nanochemistry and takes an umbrella view of the whole area. This concise textbook traces the fascinating modern practice of the chemistry of the non-covalent bond from its fundamental origins through to it expression in the emergence of nanochemistry. Fusing synthetic materials and supramolecular chemistry with crystal engineering and the emerging principles of nanotechnology, the book is an ideal introduction to current chemical thought for researchers and a superb resource for students entering these exciting areas for the first time. The book builds from first principles rather than adopting a review style and includes key references to guide the reader through influential work. supplementary website featuring powerpoint slides of the figures in the book further references in each chapter builds from first principles rather than adopting a review style includes chapter on nanochemistry clear diagrams to highlight basic principles |
| supramolecular chemistry: Supramolecular Chemistry in Biomedical Imaging Stephen Faulkner, Thorfinnur Gunnlaugsson, Gearoid O Maille, 2022-04-01 There have been great advances in biomedical imaging techniques in recent years and they are becoming prominent in supramolecular chemistry. This book will clarify the current understanding of these techniques. |
| supramolecular chemistry: Principles and Methods in Supramolecular Chemistry Hans-Jörg Schneider, Anatoly Yatsimirsky, 2000-04-14 Supramolecular chemistry is one of the most actively pursued fields of science. Its implications reach from molecular recognition in synthetic and natural complexes to exciting new applications in chemical technologies, materials, and biological and medical science. Principles and Methods in Supramolecular Chemistry gives a systematic and concise overview of this diverse subject. Particular emphasis is given to the physical principles and methods which are important in the design, characterization, and application of supramolecular systems. Features that make this monograph essential reading for graduates and researchers in this area include: * A comprehensive overview of non-covalent interactions in supramolecular complexes * A guide to characterizing such complexes by physical methods * Selected applications of synthetic supramolecular systems * Question and answer sections * Illustrations from the Author's webpage which compliment the book. |
| supramolecular chemistry: Supramolecular Protein Chemistry Peter B Crowley, 2020-12-09 Building on decades of “host-guest” research, recent years have seen a surge of activity in water-soluble supramolecular receptors for protein recognition and assembly. Progress has been particularly rich in the area of calixarenes, cucurbiturils and molecular tweezers. Emerging applications include controlled protein assembly in solution, crystal engineering, supramolecular control of catalysis (both in vitro and in vivo), as well as novel mechanisms of protein-interaction inhibition with relevance to amyloids and disease. One challenge at the interface of supramolecular chemistry and protein science is to increase interaction and collaboration between chemists and biochemists/structural biologists.This book addresses the exciting interface of supramolecular chemistry and protein science. Chapters cover supramolecular approaches to protein recognition, assembly and regulation. Principles outlined will highlight the opportunities that are readily accessible to collaborating chemists and biochemists, enriching the breadth and scope of this multidisciplinary field. Supramolecular Protein Chemistry will be of particular interest to graduate students and researchers working in supramolecular chemistry, protein science, self-assembly, biomaterials, biomedicine and biotechnology. |
| supramolecular chemistry: Encyclopedia of Supramolecular Chemistry J. L. Atwood, Jonathan W. Steed, 2004 Crystallizing a rapidly expanding interdisciplinary field and one of the most popular and newsworthy areas in contemporary chemistry, this two-volume encyclopaedia offers authoritative information with user-friendly and high-quality articles. |
| supramolecular chemistry: Analytical Methods in Supramolecular Chemistry Christoph A. Schalley, 2012 The second edition of Analytical Methods in Supramolecular Chemistry comes in two volumes and covers a broad range of modern methods and techniques now used for investigating supramolecular systems, e. g. NMR spectroscopy, mass spectrometry, extraction methods, crystallography, single molecule spectroscopy, electrochemisty, and many more. In this second edition, tutorial inserts have been introduced, making the book also suitable as supplementary reading for courses on supramolecular chemistry. All chapters have been revised and updated and four new chapters have been added. A must-have handbook for Organic and Analytical Chemists, Spectroscopists, Materials Scientists, and Ph.D. Students in Chemistry. From reviews of the first edition: This timely book should have its place in laboratories dealing with supramolecular objects. It will be a source of reference for graduate students and more experienced researchers and could induce new ideas on the use of techniques other than those usually used in the laboratory. Journal of the American Chemical Society (2008) VOL. 130, NO. 1 doi: 10.1021/ja0769649 The book as a whole or single chapters will stimulate the reader to widen his horizon in chemistry and will help him to have new ideas in his research. Anal Bioanal Chem (2007) 389:2039-2040 DOI: 10.1007/s00216-007-1677-1 |
| supramolecular chemistry: Supramolecular Organometallic Chemistry Ionel Haiduc, Frank Thomas Edelmann, 2008-11-21 Supramolecular chemistry has become not only a major field of chemistry, but is also a vivid interface between chemistry, biology, physics, and materials science. Although still a relatively young field, termini such as molecular recognition, host-guest chemistry, or self-assembly are now common knowledge even for chemistry students, and research has already been honored with a Nobel Prize. This first book on supramolecular organometallic chemistry combines two areas in chemistry that are experiencing the fastest developments. It provides a comprehensive review of various organometallic assemblies, arranged according to the types of intermolecular bonding. Details on the synthesis, structures, and properties of these compounds will be a valuable asset to the scientific community. The broad spectrum of assemblies containing main group element, transition metal, or f-element metal and a diverse range of ligands, held together by different bonding interactions make this a fascinating compilation. Illustrated extensively, this book is a very easily accessible, yet wide-ranging source of information. |
| supramolecular chemistry: Introduction to Supramolecular Chemistry Helena Dodziuk, 2007-05-08 A new rapidly progressing field on the crossroads among chemistry, biochemistry, physics and technology - supramolecular chemistry - has just emerged. You have to be involved, to know what's going on in this domain and to take part in the development. This book will show you in a condensed form exciting phenomena unthinkable within the realm of classical organic chemistry (for example, alkali metal anions or cyclobutadiene stable for month at room temperature) that not only provide the basis for revolutionizing numerous branches of industry but also improve our understanding of the functioning of living organisms and of the origin of life. Designing supramolecular systems with desired properties will among others make chemical industry cleaner and more safe, electronics smaller by developing devices composed of single molecule or molecular aggregate. It will also entirely change the way we use energy resources. In addition, it will also transform the pharmaceutical industry and medicine by developing new ways of drugs administration and new composite biocompatible materials which will serve as implants of new generation changing dentistry, surgery, and other branches of medicine. You cannot afford to stand apart. With its brief but comprehensive and vivid presentation including the latest development, Introduction to Supramolecular Chemistry is the best method to get into this domain. This book provides an excellent summary of information scattered across the literature. The brief but comprehensive coverage of the whole field including practically all important group of compounds forming aggregates (in particular crown ethers, cavitands, fullerenes, cyclodextrins and their complexes) provisioning full references for the discussed subjects make this book of value not only for Ph.D. students and non-specialists in this domain but also for those working in the field. The book has been found to be a particularly useful resource for students and more generally for those wanting to get the up-to-date concise account of this exciting field. |
| supramolecular chemistry: Supramolecular Electrochemistry Angel E. Kaifer, Marielle Gómez-Kaifer, 2008-07-11 This book describes the electrochemical behavior of supramolecular systems. Special emphasis will be given to the electrochemistry of host-guest complexes, monolayer and multilayer assemblies, dendrimers, and other supramolecular assemblies. A fundamental theme throughout the book is to explore the effects that supramolecular structure exerts on the thermodynamics and kinetics of electrochemical reactions. Conversely, attention will be placed to the various ways in which electrochemical or redox conversions can be utilized to control or affect the structure or properties of supramolecular systems. This first book on this topic will be of value for graduate students and advanced researchers in both electrochemistry and supramolecular chemistry. |
| supramolecular chemistry: Supramolecular Chemistry Jonathan W. Steed, Jerry L. Atwood, 2013-05-21 Supramolecular chemistry is ‘chemistry beyond the molecule’ - the chemistry of molecular assemblies and intermolecular bonds. It is one of today’s fastest growing disciplines, crossing a range of subjects from biological chemistry to materials science; and from synthesis to spectroscopy. Supramolecular Chemistry is an up-to-date, integrated textbook that tells the newcomer to the field everything they need to know to get started. Assuming little in the way of prior knowledge, the book covers the concepts behind the subject, its breadth, applications and the latest contemporary thinking in the area. It also includes coverage of the more important experimental and instrumental techniques needed by supramolecular chemists. The book has been thoroughly updated for this second edition. In addition to the strengths of the very popular first edition, this comprehensive new version expands coverage into a broad range of emerging areas. Clear explanations of both fundamental and nascent concepts are supplemented by up-to-date coverage of exciting emerging trends in the literature. Numerous examples and problems are included throughout the book. A system of “key references” allows rapid access to the secondary literature, and of course comprehensive primary literature citations are provided. A selection of the topics covered is listed below. Cation, anion, ion-pair and molecular host-guest chemistry Crystal engineering Topological entanglement Clathrates Self-assembly Molecular devices Dendrimers Supramolecular polymers Microfabrication Nanoparticles Chemical emergence Metal-organic frameworks Gels Ionic liquids Supramolecular catalysis Molecular electronics Polymorphism Gas sorption Anion-pinteractions Nanochemistry Supramolecular Chemistry is a must for both students new to the field and for experienced researchers wanting to explore the origins and wider context of their work. Review: At just under 1000 pages, the second edition of Steed and Atwood's Supramolecular Chemistry is the most comprehensive overview of the area available in textbook form...highly recommended. —Chemistry World, August 2009 |
| supramolecular chemistry: DNA in Supramolecular Chemistry and Nanotechnology Eugen Stulz, Guido H. Clever, 2015-09-28 This book covers the emerging topic of DNA nanotechnology and DNA supramolecular chemistry in its broader sense. By taking DNA out of its biological role, this biomolecule has become a very versatile building block in materials chemistry, supramolecular chemistry and bio-nanotechnology. Many novel structures have been realized in the past decade, which are now being used to create molecular machines, drug delivery systems, diagnosis platforms or potential electronic devices. The book combines many aspects of DNA nanotechnology, including formation of functional structures based on covalent and non-covalent systems, DNA origami, DNA based switches, DNA machines, and alternative structures and templates. This broad coverage is very appealing since it combines both the synthesis of modified DNA as well as designer concepts to successfully plan and make DNA nanostructures. Contributing authors have provided first a general introduction for the non-specialist reader, followed by a more in-depth analysis and presentation of their topic. In this way the book is attractive and useful for both the non-specialist who would like to have an overview of the topic, as well as the specialist reader who requires more information and inspiration to foster their own research. |
| supramolecular chemistry: Supramolecular Chemistry in Water Stefan Kubik, 2019-05-16 Provides deep insight into the concepts and recent developments in the area of supramolecular chemistry in water Written by experts in their respective field, this comprehensive reference covers various aspects of supramolecular chemistry in water?from fundamental aspects to applications. It provides readers with a basic introduction to the current understanding of the properties of water and how they influence molecular recognition, and examines the different receptor types available in water and the types of substrates that can be bound. It also looks at areas to where they can be applied, such as materials, optical sensing, medicinal imaging, and catalysis. Supramolecular Chemistry in Water offers five major sections that address important topics like water properties, molecular recognition, association and aggregation phenomena, optical detection and imaging, and supramolecular catalysis. It covers chemistry and physical chemistry of water; water-mediated molecular recognition; peptide and protein receptors; nucleotide receptors; carbohydrate receptors; and ion receptors. The book also teaches readers all about coordination compounds; self-assembled polymers and gels; foldamers; vesicles and micelles; and surface-modified nanoparticles. In addition, it provides in-depth information on indicators and optical probes, as well as probes for medical imaging. -Covers, in a timely manner, an emerging area in chemistry that is growing more important every day -Addresses topics such as molecular recognition, aggregation, catalysis, and more -Offers comprehensive coverage of everything from fundamental aspects of supramolecular chemistry in water to its applications -Edited by one of the leading international scientists in the field Supramolecular Chemistry in Water is a one-stop-resource for all polymer chemists, catalytic chemists, biochemists, water chemists, and physical chemists involved in this growing area of research. |
| supramolecular chemistry: Supramolecular Systems in Biomedical Fields Hans-Jörg Schneider, 2013-09-06 Non-covalent interactions, which are the heart of supramolecular chemistry are also the basis of most important functions of living systems. The ability to apply supramolecular chemistry principles to the life sciences, such as designing synthetic host compounds to selectively interact within biological targets, has gained wide appeal due the vast number of potential applications. Supramolecular Systems for Biomedical Fields provides in sixteen chapters a comprehensive overview of these applications. Each chapter covers a specific topic and is written by internationally renowned experts in that area. Sensing of bioactive inorganic ions and organic substrates is the focus of several contributions, as well as interactions with proteins and nucleic acids. Specific chapters are devoted to cyclodextrins, calixarenes and cucurbiturils as most frequently used receptors, including applications such as drug delivery and protection, gene transfer and others. Other chapters address the use of combinatorial libraries, molecular imprinting techniques, enzyme assays, supramolecular gels, bioimaging, drug activation, photodynamic therapy, and antitumour metal complexes. This timely publication will appeal to graduate students and researchers from chemical, pharmaceutical, biological, and medicinal fields interested in the supramolecular chemistry of biological systems and their practical potentials. |
| supramolecular chemistry: A Practical Guide to Supramolecular Chemistry Peter J. Cragg, 2005-11-04 A Practical Guide to Supramolecular Chemistry is an introductory manual of practical experiments for chemists with little or no prior experience of supramolecular chemistry. Syntheses are clearly presented to facilitate the preparation of acyclic and macrocyclic compounds frequently encountered in supramolecular chemistry using straightforward experimental procedures. Many of the compounds can be used to illustrate classic supramolecular phenomena, for which clear directions are given, or may be developed further as part of the reader’s own research. The book also describes techniques commonly used in the analysis of supramolecular behaviour, including computational methods, with many detailed examples. An invaluable reference for students and researchers in the field embarking on supramolecular chemistry projects and looking for a ‘tried and tested’ route into the chemistry of key compounds. An introductory guide to practical syntheses focusing on supramolecular chemistry. Fully referenced introductions explain the historical and contemporary importance of each compound Supplementary website including 3D molecular structures, FAQ’s about syntheses and suggestions for further experiments |
| supramolecular chemistry: Anion Receptor Chemistry Jonathan L Sessler, Philip Gale, Won-Seob Cho, 2007-10-31 Anion recognition plays a critical role in a range of biological processes, and a variety of receptors and carriers can be found throughout the natural world. Chemists working in the area of supramolecular chemistry have created a range of anion receptors, drawing inspiration from nature as well as their own inventive processes. This book traces the origins of anion recognition chemistry as a unique sub-field in supramolecular chemistry while illustrating the basic approaches currently being used to effect receptor design. The combination of biological overview and summary of current synthetic approaches provides a coverage that is both comprehensive and comprehensible. First, the authors detail the key design motifs that have been used to generate synthetic receptors and which are likely to provide the basis for further developments. They also highlight briefly some of the features that are present in naturally occurring anion recognition and transport systems and summarise the applications of anion recognition chemistry. Providing as it does a detailed review for practitioners in the field and a concise introduction to the topic for newcomers, Anion Receptor Chemistry reflects the current state of the art. Fully referenced and illustrated in colour, it is a welcome addition to the literature. |
| supramolecular chemistry: New Trends in Macromolecular and Supramolecular Chemistry for Biological Applications Marc J.M. Abadie, Mariana Pinteala, Alexandru Rotaru, 2022-05-29 This contributed volume applies the insights of supramolecular chemistry to biomedical applications such as ions/water transport through nano-scale channels, gene therapy, tissue engineering and drug delivery, to cite some of the major investigations.The challenge is to understand the mechanisms of transport through tissues particularly in the therapeutic treatment of a disease where the active drug must be delivered directly to diseased cells without affecting healthy cells. As a result, smaller quantities of active substances can be used to treat the disease. Another interest concerns new ways to administer gene therapy. If genes are often delivered to their target cells by adapted viruses, the supramolecular non-viral ‘vectors’ using dynamic nano-frameworks and nano-structures are presented. In addition, it is important to reconstruct damaged tissues by mimicking natural processes in cells and polymers, such as tissue engineering and self-healing. Different options are here discussed: e.g. hydrogels based on chitosan, a carbohydrate polymer, are proving especially promising for tissue engineering and drug delivery. For controlled delivery of drugs or other biologically active compounds, hydrogels sensitive to the most important stimuli in the human body, such as temperature, pH, ionic strength, glucose and biomolecules released by the organism in pathological conditions have been developed. Finally, to assist and validate the experimental studies, computer modelling and simulations of large-sized molecular structures and systems using different molecular dynamics and quantum mechanical techniques are developed based on the experimental and chemistry synthesis. This book is of great interest for graduate students, researchers and health professionals interested in acquiring a better understanding of the mechanisms of medical treatments. In addition, it provides numerous tools to develop better therapies for human diseases. |
| supramolecular chemistry: Introduction to Supramolecular Chemistry Helena Dodziuk, 2002 A supermolecule is composed of molecules and/or ions held together by weak nonbonding interactions. The interactions can dramatically change the properties of constituent parts of the association. Dodziuk (Institute of Physical Chemistry, Polish Academy of Sciences, Poland) explains the emerging field related to these bodies that is interacting with the domains of chemistry, physics, biology, and technology. After giving an account of general ideas constituting the basis of the interdisciplinary field, present and future applications are presented. A brief overview of important groups of compounds and systems involved, especially the macrocyclic ligands, is also presented. Annotation copyrighted by Book News Inc., Portland, OR. |
| supramolecular chemistry: Anion Recognition in Supramolecular Chemistry Philip A. Gale, Wim Dehaen, 2010-09 Brett M. Rambo ∙ Eric S. Silver ∙ Christopher W. Bielawski ∙ Jonathan L. Sessler Covalent Polymers Containing Discrete Heterocyclic Anion Receptors Philip A. Gale ∙ Chang-Hee Lee Calix[n]pyrroles as Anion and Ion-Pair Complexants Wim Dehaen Calix[n]phyrins: Synthesis and Anion Recognition Hiromitsu Maeda Acyclic Oligopyrrolic Anion Receptors Jeffery T. Davis Anion Binding and Transport by Prodigiosin and Its Analogs Hemraj Juwarker ∙ Jae-min Suk ∙ Kyu-Sung Jeong Indoles and Related Heterocycles Pavel Anzenbacher Jr. Pyrrole-Based Anion Sensors, Part I: Colorimetric Sensors Pavel Anzenbacher Jr. Pyrrole-Based Anion Sensors, Part II: Fluorescence, Luminescence, and Electrochemical Sensors Ermitas Alcalde ∙ Immaculada Dinarès ∙ Neus Mesquida Imidazolium-Based Receptors Nathan L. Kilah ∙ Paul D. Beer Pyridine and Pyridinium-Based Anion Receptors Kevin P. McDonald ∙ Yuran Hua ∙ Amar H. Flood 1,2,3-Triazoles and the Expanding Utility of Charge Neutral CHlllAnion Interactions |
| supramolecular chemistry: Supramolecular Nucleic Acid Chemistry James Tucker, Janarthanan Jayawickramarajah, 2020-10-28 This eBook is a collection of articles from a Frontiers Research Topic. Frontiers Research Topics are very popular trademarks of the Frontiers Journals Series: they are collections of at least ten articles, all centered on a particular subject. With their unique mix of varied contributions from Original Research to Review Articles, Frontiers Research Topics unify the most influential researchers, the latest key findings and historical advances in a hot research area! Find out more on how to host your own Frontiers Research Topic or contribute to one as an author by contacting the Frontiers Editorial Office: frontiersin.org/about/contact. |
| supramolecular chemistry: Synergy in Supramolecular Chemistry Tatsuya Nabeshima, 2014-12-18 Cooperative and synergistic chemical events have attracted significant attention from many researchers engaged in organic chemistry, inorganic chemistry, biological chemistry, polymer chemistry, medicinal chemistry, and other related materials sciences. Synergistic supramolecular systems could be developed to amplify the functions and integration o |
| supramolecular chemistry: Modern Supramolecular Gold Chemistry Antonio Laguna, 2008-09-26 Filling a gap in our systematic knowledge of gold, this monograph covers the fundamental aspects, while also considering new applications of gold compounds in catalysis, as nanoparticles, and their potential application as luminescent compounds. Written by an eminent team of authors from academia, the book analyzes the current status of gold chemistry, its special characteristics, oxidation states and main type of complexes, before going on to look at the synthesis of supramolecular aggregates due to the formation of gold-gold, gold-metal interactions or other secondary bonds. Final sections deal with LEDs, solvoluminescent and electroluminescent materials, liquid crystals and catalysis. While of interest to advanced chemistry students, this book is also useful for researchers interested in the chemistry of gold and its applications, as well as those involved in metal-metal interactions, heteronuclear chemistry or in the optical properties of coordination compounds. |
| supramolecular chemistry: Multivalency Jurriaan Huskens, Leonard J. Prins, Rainer Haag, Bart Jan Ravoo, 2017-12-01 Connects fundamental knowledge of multivalent interactions with current practice and state-of-the-art applications Multivalency is a widespread phenomenon, with applications spanning supramolecular chemistry, materials chemistry, pharmaceutical chemistry and biochemistry. This advanced textbook provides students and junior scientists with an excellent introduction to the fundamentals of multivalent interactions, whilst expanding the knowledge of experienced researchers in the field. Multivalency: Concepts, Research & Applications is divided into three parts. Part one provides background knowledge on various aspects of multivalency and cooperativity and presents practical methods for their study. Fundamental aspects such as thermodynamics, kinetics and the principle of effective molarity are described, and characterisation methods, experimental methodologies and data treatment methods are also discussed. Parts two and three provide an overview of current systems in which multivalency plays an important role in chemistry and biology, with a focus on the design rules, underlying chemistry and the fundamental principles of multivalency. The systems covered range from chemical/materials-based ones such as dendrimers and sensors, to biological systems including cell recognition and protein binding. Examples and case studies from biochemistry/bioorganic chemistry as well as synthetic systems feature throughout the book. Introduces students and young scientists to the field of multivalent interactions and assists experienced researchers utilising the methodologies in their work Features examples and case studies from biochemistry/bioorganic chemistry, as well as synthetic systems throughout the book Edited by leading experts in the field with contributions from established scientists Multivalency: Concepts, Research & Applications is recommended for graduate students and junior scientists in supramolecular chemistry and related fields, looking for an introduction to multivalent interactions. It is also highly useful to experienced academics and scientists in industry working on research relating to multivalent and cooperative systems in supramolecular chemistry, organic chemistry, pharmaceutical chemistry, chemical biology, biochemistry, materials science and nanotechnology. |
| supramolecular chemistry: Functional Supramolecular Materials Rahul Banerjee, 2017-05-05 Supramolecular materials have a great number of applications due to the reversibility of their non-covalent molecular interactions, such as reversible hydrogen bonding, host–guest interactions and electrostatic interactions. This book provides a comprehensive source of information on the structure and function of organic and metal–organic supramolecular materials. The chapters of this book provide an overview of supramolecular material assembly at various scales, including the formation of 2D polymers and molecular cages. The role of intermolecular interactions in solid and solution state self-assembly is discussed, as is the role of mechanochemistry on molecular and supramolecular architectures. Finally, novel applications of these materials in molecular recognition, catalysis, light harvesting and environmental remediation are covered. Functional Supramolecular Materials will be of interest to graduate students and researchers in academia and industry in the fields of supramolecular chemistry and functional materials science. |
| supramolecular chemistry: Bioorganic, Bioinorganic and Supramolecular Chemistry P. S. Kalsi, 2007 |
| supramolecular chemistry: Porphyrin-based Supramolecular Architectures Shengqian Ma, Gaurav Verma, 2021-12-03 Porphyrin-based Supramolecular Architectures focuses on the most recent developments in the field, emphasizing the cutting-edge research in a diverse range of applications. Designed for readers considering the unprecedented prosperity of porous materials research, chapters will cover both strategies for structure design (such as MOFs and COFs) as well as emerging applications including CO2 fixation, catalysis and photodynamic therapy. With contributions from global experts, this title will be of interest to graduate students and researchers in supramolecular chemistry, organic chemistry, inorganic chemistry, physical chemistry, organometallic chemistry, solid-state chemistry, catalysis and (porous) materials science. |
| supramolecular chemistry: Computational Approaches in Supramolecular Chemistry G. Wipff, 1994-03-31 Supramolecular chemistry has been defined by J.-M. Lehn as a highly interdisciplinary field of science covering the chemical, physical, and biological features of chemical species of higher complexity, that are held together and organized by means of intermolecular (noncovalent) binding interactions (Science, 1993). Recognition, reactivity, and transport represent three basic functional features, in essence dynami~s, which may be translated into structural features. The purpose of the NATO workshop which took place september 1-5, 1993 at the Bischenberg (near Strasbourg) was to present computations which may contribute to the atomic level understanding of the structural and thermodynamical features involved in the processes of molecular recognition and supramolecular organization. of supra-molecular modeling. Other The main focus was therefore, on the many facets applications of computers in chemistry, such as automation, simulation of processes, procedures for fitting kinetic or thermodynamic data, computer assisted synthetic strategies, use of data bases for structure elucidation or for bibliographic searches, have an obvious impact in supramolecular chemistry as well, but were not presented at the workshop. |
| supramolecular chemistry: NMR in Supramolecular Chemistry Miquel Pons, 1999-03-31 NMR is better suited than any other experimental technique for the characterization of supramolecular systems in solution. The presentations included here can be broadly divided into three classes. The first class illustrates the state of the art in the design of supramolecular systems and includes examples of different classes of supramolecular complexes: catenanes, rotaxanes, hydrogen-bonded rosettes, tubes, capsules, dendrimers, and metal-containing hosts. The second class comprises contributions to NMR methods that can be applied to address the main structural problems that arise in supramolecular chemistry. The third class includes biological supramolecular systems studied by state-of-the-art NMR techniques. |
| supramolecular chemistry: Supramolecular Chemistry of Fullerenes and Carbon Nanotubes Nazario Martin, Jean-Francois Nierengarten, 2012-09-21 Collating our current knowledge and the latest developments for enabling breakthrough discoveries, this book focuses on the synthesis and applications of materials that are based on supramolecular assemblies of carbon nanostructures, with an emphasis on fullerenes and nanotubes. In so doing, it provides readers with an overview of the different types of supramolecular architectures, accentuating the outstanding geometrical, electronic and photophysical properties of the building blocks and the resulting structures. It makes use of basic concepts and real-life applications -- from simple syntheses to complex architectures, from instructive examples to working experimental procedures, and from photophysics to solar cells. A large part of each chapter is devoted to the methods and possibilities of controlling and tuning these molecular assemblies in order to obtain working devices. Fascinating reading for materials scientists, organic chemists, molecular physicists, and those in the semiconductor industry. |
| supramolecular chemistry: Supramolecular Chemistry of Anions Antonio Bianchi, Kristin Bowman-James, Enrique García-Espana, 1997-01-31 Despite the central role anionic species have been shown to play in both mineralogical and biological processes, until now there have been no comprehensive references dealing exclusively with anionic coordination chemistry. Written by a group comprising pioneering researchers from the United States and Europe, Supramolecular Chemistry of Anions covers all theoretical and practical aspects of anion complexation, from thermodynamics and structure to catalysis and various applications. The authors begin with the 1967 discovery of halide inclusion by bicyclic diammonium receptors and trace the development of anion coordination chemistry through the most recent developments in the field. Topics covered in detail include: * Pre-supramolecular anion chemistry * Natural and artificial molecules that can act as anion receptors * Preorganization and chemical design * Structural, thermodynamic, electrochemical, and photochemical aspects of anion coordination * Computer methods for receptor design and multiple host-guest relations * Anion receptor catalysis and molecular recognition and transformation of nucleotides Supramolecular Chemistry of Anions is a valuable professional resource for organic and inorganic chemists, analytical chemists, biotechnologists, pharmaceutical scientists, and environmental chemists. It also serves as an excellent graduate-level text for students of molecular recognition, catalysis, and biomimetic chemistry. |
| supramolecular chemistry: Supramolecular Chemistry, 8 Volume Set , 2012-03-05 Supramolecular Chemistry: From Molecules to Nanomaterials is a new major reference work which links supramolecular chemistry and nanomaterials. Presenting over 150 tutorial articles and spanning over 10 comprehensive sections, this new resource covers: Concepts Techniques Molecular recognition Supramolecular reactivity Supramolecular aspects of chemical biology Self processes Supramolecular devices Supramolecular materials chemistry Soft matter Nanotechnology Supramolecular chemistry is 'chemistry beyond the molecule'. While traditional chemistry focuses on the bonds that hold atoms together in a molecule, supramolecular chemistry examines the weaker interactions that hold groups of molecules together. Important concepts that have been demonstrated by supramolecular chemistry include molecular self-assembly, folding, molecular recognition, host-guest chemistry, mechanically-interlocked molecular architectures, and dynamic covalent chemistry. The importance of supramolecular chemistry was established by the 1987 Nobel Prize for Chemistry, which was awarded to Donald J. Cram, Jean-Marie Lehn, and Charles J. Pedersen in recognition of their work in the field. The past decade has seen dramatic developments in the field, with supramolecular chemistry leaving its roots in classical host guest chemistry and expanding into exciting areas of materials chemistry and nanoscience with many real and potential applications. Supramolecular findings are evolving our understanding of the way chemical concepts at the molecular level build up into materials and systems with fascinating, emergent properties on the nanoscale. Supramolecular chemistry: the biggest challenge yet! Creating that link between the chemist's understanding of the way in which molecules interact with one another, and the understanding a materials scientist, engineer or biologist has of the resulting properties of a material or system comprised of those molecules is one of the huge grand challenges facing modern molecular science. —Philip A. Gale and Jonathan W. Steed, Editors-in-Chief Linking supramolecular chemistry and nanotechnology to define the field in the 21st Century… Supramolecular Chemistry: From Molecules to Nanomaterials is the first major reference to link supramolecular chemistry and nanotechnology. A global team of experts present an overview of the concepts and techniques of modern supramolecular chemistry, demonstrating how these paradigms evolve into nanoscale systems chemistry, nanotechnology, materials science and beyond. Breaking down the barriers between synthetic chemistry and materials science, the authors demonstrate how modern techniques allow access increasingly far along the 'synthesising-up' pathway. Supramolecular Chemistry: From Molecules to Nanomaterials explains the fundamental concepts and provides invaluable practical guidance on the applications and limitations of modern instrumental techniques for addressing molecular and materials-based problems. The printed edition of Supramolecular Chemistry: From Molecules to Nanomaterials is available as an eight-volume set. Publishing in full colour to enhance the interpretation of complex supramolecular structures the printed edition is highly illustrated with an average of three images per page features fully indexed articles with cross-references integrated into the text includes a glossary of key terms Online Edition Supramolecular Chemistry: From Molecules to Nanomaterials is now available online. For further information visit WileyOnlineLibrary.com/ref/smc |
| supramolecular chemistry: Supramolecular Chemistry on Surfaces Neil R. Champness, 2021-12-09 Supramolecular Chemistry on Surfaces 2D Networks and 2D Structures Explore the cutting-edge in 2D chemistry on surfaces and its applications In Supramolecular Chemistry on Surfaces: 2D Networks and 2D Structures, expert chemist Neil R. Champness delivers a comprehensive overview of the rapidly developing field of two-dimensional supramolecular chemistry on surfaces. The book offers explorations of the state-of-the-art in the discipline and demonstrates the potential of the latest advances and the challenges faced by researchers in different areas. The editor includes contributions from leading researchers that address new spectroscopic methods which allow for investigations at a sub-molecular level, opening up new areas of understanding in the field. Included resources also discuss important supramolecular strategies, like hydrogen-bonding, van der Waals interactions, metal-ligand coordination, multicomponent assembly, and more. The book also provides: A thorough introduction to two-dimensional supramolecular chemistry on surfaces Comprehensive explorations of the characterization and interpretation of on-surface chemical reactions studied by ultra-high resolution scanning probe microscopy Practical discussions of complexity in two-dimensional multicomponent assembly, including explorations of coordination bonds and quasicrystalline structures In-depth examinations of covalently bonded organic structures via on-surface synthesis Perfect for polymer chemists, spectroscopists, and materials scientists, Supramolecular Chemistry on Surfaces: 2D Networks and 2D Structures will also earn a place in the libraries of physical and surface chemists, as well as surface physicists. |
| supramolecular chemistry: Supramolecular Science Rocco Ungaro, Enrico Dalcanale, 2012-12-06 A summary of all the most important aspects of supramolecular science, from molecular recognition in chemical and biological systems to supramolecular devices, materials and catalysis. The 17 chapters cover calixarenes, catenanes, cavitands, cholophanes, dendrimers, membranes and self-assembly systems, molecular modelling, molecular level devices, organic materials, peptides and protein surfaces, recognition of carbohydrates, rotaxanes, supramolecular catalysis. A forward-looking chapter written by J.-M. Lehn indicated the future prospects for the entire field. Audience: Ph.D. students and young researchers in chemistry, physics and biology. |
| supramolecular chemistry: Supramolecular Photochemistry Vincenzo Balzani, 2012-12-06 The intellectual and utilitarian opportunities that lie at the frontiers of chemistry have been recently emphasized by the Pimentel Report. Such report recommends that in the field of chemical research priority should be given to understanding chemical reactivity and proposes initiatives aimed at the clarification of factors that control the rates of reaction and the development of new synthetic pathways for chemical change. In the broad field of chemical reactivity, a discipline that has grown with an extraordinary rate is photochemistry. Since the knowledge of the photochemical properties at the molecular level has made a substantial progress in the last few years, there is currently a trend to study more and more complex photochemical systems. In particular, an emerging and rapidly expanding branch of photochemistry is that concerning studies of assemblies of molecular components properly combined so as to obtain light-induced functions (supramolecular photochemistry). Although much of the current work in supramolecular photochemistry is fundamental in nature, it is clear that progress in this field will be most rewarding for several applications concerning the interaction of light with matter. In particular, it will allow us to pursue research aimed at the photochemical conversion of solar energy by means of artificial systems and to make progress towards futuristic branches of science called photonics (photo-generated electron migration processes on a molecular basis) and chemionics (design of components, circuitry, and information treatment at the molecular level). |
| supramolecular chemistry: Host–Guest Chemistry Brian D. Wagner, 2020-10-26 This textbook addresses the chemical and physicochemical principles of supramolecular host-guest chemistry in solution. It covers the thermodynamics and dynamics of inclusion and highlights several types of organic hosts. Various applications of host-guest chemistry in analytical and environmental chemistry as well as pharmaceutical and chemical industry demonstrate the versatile usability of molecular cages. |
Supramolecular Chemistry - Nature
Jun 9, 2022 · Supramolecular chemistry specializes in non-covalent interactions. These weak and reversible forces are key to understanding biological processes and …
Supramolecular chemistry - Latest research and news - Nature
May 23, 2025 · Supramolecular chemistry is the study of entities of greater complexity than individual molecules — assemblies of molecules that bond and organize through …
Supramolecular systems chemistry - Nature Nanotechnology
Feb 5, 2015 · The field of supramolecular chemistry focuses on the non-covalent interactions between molecules that give rise to molecular recognition and self …
Chemistry beyond the molecule - Nature
Jul 26, 2001 · Supramolecular chemistry has grown in importance because it goes beyond the molecule — the focus of classical chemistry. It also offers a fresh interface …
Supramolecular chemistry - Nature
May 12, 2025 · In reticular chemistry, the formation of strong chemical bonds between molecular components is typically considered a core prerequisite for synthesizing open …
Supramolecular Chemistry - Nature
Jun 9, 2022 · Supramolecular chemistry specializes in non-covalent interactions. These weak and reversible forces are …
Supramolecular chemistry - Latest research and news - N…
May 23, 2025 · Supramolecular chemistry is the study of entities of greater complexity than individual …
Supramolecular systems chemistry - Nature Nanotech…
Feb 5, 2015 · The field of supramolecular chemistry focuses on the non-covalent interactions …
Chemistry beyond the molecule - Nature
Jul 26, 2001 · Supramolecular chemistry has grown in importance because it goes beyond the molecule — the …
Supramolecular chemistry - Nature
May 12, 2025 · In reticular chemistry, the formation of strong chemical bonds between molecular components is …
