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| nmr spectroscopy in inorganic chemistry: NMR Spectroscopy in Inorganic Chemistry Jonathan A. Iggo, Konstantin Luzyanin, 2020 La 4e de couverture indique Offering a concise and accessible conceptual grounding in the general physical principles underlying NMR spectroscopy, including NMR spectroscopy of nuclei other than 1H, this new edition of NMR Spectrocopy in Inorganic Chemistry introduces students to the basics of predicting NMR spectra. The text then builds on that understanding to cover more challenging concepts, such as factors influencing the chemical shift, coupling constants, and dynamic NMR spectroscopy. |
| nmr spectroscopy in inorganic chemistry: NMR Spectroscopy in Inorganic Chemistry Jonathan A. Iggo, 1999 |
| nmr spectroscopy in inorganic chemistry: NMR Spectroscopy in Inorganic Chemistry Jonathan A. Iggo, Konstantin Luzyanin, 2020 |
| nmr spectroscopy in inorganic chemistry: Structural Methods in Molecular Inorganic Chemistry D. W. H. Rankin, Norbert Mitzel, Carole Morrison, 2013-01-02 Determining the structure of molecules is a fundamental skill that all chemists must learn. Structural Methods in Molecular Inorganic Chemistry is designed to help readers interpret experimental data, understand the material published in modern journals of inorganic chemistry, and make decisions about what techniques will be the most useful in solving particular structural problems. Following a general introduction to the tools and concepts in structural chemistry, the following topics are covered in detail: • computational chemistry • nuclear magnetic resonance spectroscopy • electron paramagnetic resonance spectroscopy • Mössbauer spectroscopy • rotational spectra and rotational structure • vibrational spectroscopy • electronic characterization techniques • diffraction methods • mass spectrometry The final chapter presents a series of case histories, illustrating how chemists have applied a broad range of structural techniques to interpret and understand chemical systems. Throughout the textbook a strong connection is made between theoretical topics and the real world of practicing chemists. Each chapter concludes with problems and discussion questions, and a supporting website contains additional advanced material. Structural Methods in Molecular Inorganic Chemistry is an extensive update and sequel to the successful textbook Structural Methods in Inorganic Chemistry by Ebsworth, Rankin and Cradock. It is essential reading for all advanced students of chemistry, and a handy reference source for the professional chemist. |
| nmr spectroscopy in inorganic chemistry: Nuclear Magnetic Resonance Spectroscopy of Boron Compounds Heinrich Nöth, Bernd Wrackmeyer, 2012-12-06 The revolutionary impetus of the NMR methods in organic chemistry has parallels in the field of boron chemistry. lIB NMR spectroscopy provided a basis for the elucida tion of structures and reactions of the boron hydrides. However, although many studies have been carried out with the higher boranes, carboranes, metalloboranes, etc. , and although certain patterns have emerged, the correlation between the observed chemical shift and the assigned structural unit is still not fully understood. Therefore, predictions in this area are still rather limited, and semiquantitative interpretations are not yet pos sible. Several years ago Eaton and Lipscomb sUpImarized the status in this field in their book NMR Studies of Boron Hydrides and Related Compounds and a plethora of new data has accumulated since then. The book also contained material on simple bo rane derivatives, but they were not discussed in any detail. On the other hand many systematic studies, both synthetic and spectroscopic, have been conducted on these simple boron materials in the last decade. Thus a large amount of NMR information is available, not only on lIB but also on 1 H, 1 3 C, and 14 N. However, this information is widely scattered in the literature, and often the data are not discussed at all. It see med appropriate, therefore, to collect these data and to present them in one volume. |
| nmr spectroscopy in inorganic chemistry: High-resolution NMR Techniques in Organic Chemistry T. Claridge, 1999-12-24 From the initial observation of proton magnetic resonance in water and in paraffin, the discipline of nuclear magnetic resonance has seen unparalleled growth as an analytical method. Modern NMR spectroscopy is a highly developed, yet still evolving, subject which finds application in chemistry, biology, medicine, materials science and geology. In this book, emphasis is on the more recently developed methods of solution-state NMR applicable to chemical research, which are chosen for their wide applicability and robustness. These have, in many cases, already become established techniques in NMR laboratories, in both academic and industrial establishments. A considerable amount of information and guidance is given on the implementation and execution of the techniques described in this book. |
| nmr spectroscopy in inorganic chemistry: Advanced Applications of NMR to Organometallic Chemistry Marcel Gielen, Rudolph Willem, Bernd Wrackmeyer, 1996-12-23 This new series offers leading contributions by well known chemists reviewing the state-of-the-art of this wide research area. Physical Organometallic Chemistry aims to develop new insights and to promote novel interest and investigations applicable to organometallic chemistry. NMR spectroscopy has had a considerable impact on many fields of chemistry, although it has served organometallic chemistry mainly on a routine level. In a collection of reviews, leading chemists provide an insight into the scope of applications and uncover the potential of this technique for organometallic chemists. Advanced Applications of NMR to Organometallic Chemistry; Illustrates how recent 1D and 2D and specialized multinuclear applications can solve specific problems encountered by organometallic chemists Surveys modern NMR techniques in organometallic chemistry Includes metal NMR related techniques Focuses on the advent of solid state NMR in organometallic chemistry This book will prove invaluable to the NMR spectroscopist and organometallic chemists and will also be of interest to all organic, inorganic and physical chemists Contents: Selective Excitation and Selective Detection in 29Si NMR; Two-dimensional 13C, Metal Nuclei Correlation; Two-dimensional 1H-119Sn Proton Detected Correlation Spectroscopy in Coordination Chemistry of Hypervalent Organotin Compounds; Indirect Nuclear 119Sn-X Spin-Spin Coupling; Solid State NMR Applications in Organotin and Organolead Chemistry; Solid State NMR Investigations of Metal Carbonyl Complexes; High Pressure NMR in Organometallic Chemistry; Multinuclear NMR Spectroscopy in Supercritical Fluids; High Resolution 6,7Li NMR of Organolithium Compounds; Metal NMR of Organovanadium, -Niobium and -Tantalum Compounds; NMR of Metallic Nuclei in Clusters; 171Yb NMR Spectroscopy. |
| nmr spectroscopy in inorganic chemistry: Practical Approaches to Biological Inorganic Chemistry Robert R. Crichton, Ricardo O. Louro, 2012-12-31 The book reviews the use of spectroscopic and related methods to investigate the complex structures and mechanisms of biological inorganic systems that contain metals. Each chapter presents an overview of the technique including relevant theory, clearly explains what it is and how it works and then presents how the technique is actually used to evaluate biological structures. Practical examples and problems are included to illustrate each technique and to aid understanding. Designed for students and researchers who want to learn both the basics, and more advanced aspects of bioinorganic chemistry. - Many colour illustrations enable easier visualization of molecular mechanisms and structures - Worked examples and problems are included to illustrate and test the reader's understanding of each technique - Written by a multi-author team who use and teach the most important techniques used today to analyse complex biological structures |
| nmr spectroscopy in inorganic chemistry: Multinuclear NMR J. Mason, 2012-12-06 With the power and range of modern pulse spectrometers the compass of NMR spec troscopy is now very large for a single book-but we have undertaken this. Our book covers the Periodic Table as multinuclear spectrometers do, and introductory chapters are devoted to the essentials of the NMR experiment and its products. Primary products are chemical shifts (including anisotropies), spin-spin coupling constants, and relaxation times; the ultimate product is a knowledge of content and constitution, dynamic as well as static. Our province is chemical and biochemical rather than physical or technical; only passing reference is made to metallic solids or unstable species, or to practical NMR spectroscopy. Our aim is depth as well as breadth, to explain the fundamental processes, whether of nuclear magnetic shielding, spin-spin coupling, relaxation, or the multiple pulse sequences that have allowed the development of high-resolution studies of solids, multidimensional NMR spectroscopy, techniques for sensitivity enhancement, and so on. This book therefore combines the functions of advanced textbook and reference book. For reasonably comprehensive coverage in a single volume we have sum marized the information in tables and charts, and included all leading references. |
| nmr spectroscopy in inorganic chemistry: Nuclear Magnetic Resonance Spectroscopy Joseph B. Lambert, Eugene P. Mazzola, Clark D. Ridge, 2018-10-25 Combines clear and concise discussions of key NMR concepts with succinct and illustrative examples Designed to cover a full course in Nuclear Magnetic Resonance (NMR) Spectroscopy, this text offers complete coverage of classic (one-dimensional) NMR as well as up-to-date coverage of two-dimensional NMR and other modern methods. It contains practical advice, theory, illustrated applications, and classroom-tested problems; looks at such important ideas as relaxation, NOEs, phase cycling, and processing parameters; and provides brief, yet fully comprehensible, examples. It also uniquely lists all of the general parameters for many experiments including mixing times, number of scans, relaxation times, and more. Nuclear Magnetic Resonance Spectroscopy: An Introduction to Principles, Applications, and Experimental Methods, 2nd Edition begins by introducing readers to NMR spectroscopy - an analytical technique used in modern chemistry, biochemistry, and biology that allows identification and characterization of organic, and some inorganic, compounds. It offers chapters covering: Experimental Methods; The Chemical Shift; The Coupling Constant; Further Topics in One-Dimensional NMR Spectroscopy; Two-Dimensional NMR Spectroscopy; Advanced Experimental Methods; and Structural Elucidation. Features classical analysis of chemical shifts and coupling constants for both protons and other nuclei, as well as modern multi‐pulse and multi-dimensional methods Contains experimental procedures and practical advice relative to the execution of NMR experiments Includes a chapter-long, worked-out problem that illustrates the application of nearly all current methods Offers appendices containing the theoretical basis of NMR, including the most modern approach that uses product operators and coherence-level diagrams By offering a balance between volumes aimed at NMR specialists and the structure-determination-only books that focus on synthetic organic chemists, Nuclear Magnetic Resonance Spectroscopy: An Introduction to Principles, Applications, and Experimental Methods, 2nd Edition is an excellent text for students and post-graduate students working in analytical and bio-sciences, as well as scientists who use NMR spectroscopy as a primary tool in their work. |
| nmr spectroscopy in inorganic chemistry: Spectroscopy for Materials Characterization Simonpietro Agnello, 2021-08-23 SPECTROSCOPY FOR MATERIALS CHARACTERIZATION Learn foundational and advanced spectroscopy techniques from leading researchers in physics, chemistry, surface science, and nanoscience In Spectroscopy for Materials Characterization, accomplished researcher Simonpietro Agnello delivers a practical and accessible compilation of various spectroscopy techniques taught and used to today. The book offers a wide-ranging approach taught by leading researchers working in physics, chemistry, surface science, and nanoscience. It is ideal for both new students and advanced researchers studying and working with spectroscopy. Topics such as confocal and two photon spectroscopy, as well as infrared absorption and Raman and micro-Raman spectroscopy, are discussed, as are thermally stimulated luminescence and spectroscopic studies of radiation effects on optical materials. Each chapter includes a basic introduction to the theory necessary to understand a specific technique, details about the characteristic instrumental features and apparatuses used, including tips for the appropriate arrangement of a typical experiment, and a reproducible case study that shows the discussed techniques used in a real laboratory. Readers will benefit from the inclusion of: Complete and practical case studies at the conclusion of each chapter to highlight the concepts and techniques discussed in the material Citations of additional resources ideal for further study A thorough introduction to the basic aspects of radiation matter interaction in the visible-ultraviolet range and the fundamentals of absorption and emission A rigorous exploration of time resolved spectroscopy at the nanosecond and femtosecond intervals Perfect for Master and Ph.D. students and researchers in physics, chemistry, engineering, and biology, Spectroscopy for Materials Characterization will also earn a place in the libraries of materials science researchers and students seeking a one-stop reference to basic and advanced spectroscopy techniques. |
| nmr spectroscopy in inorganic chemistry: Assigning Inorganic NMR Spectra Michael O'Neill, 2019-10-23 Teach yourself how to assign the complex NMR spectra of main group molecules.This book offers advanced chemistry students the opportunity to engage deeply with the skill of assigning inorganic NMR spectra. Beginning simply, the book challenges you with a sequence of problems on environments, quadrupolar splitting, and spin dilution. Using worked answers, you self-mark your own answers to gain all the skills you need.Short interludes teach Hz-ppm conversions, the use of decoupling, molecular fluxionality, and how to calculate energetic barriers using VT-NMR. |
| nmr spectroscopy in inorganic chemistry: Modern NMR Spectroscopy Jeremy K. M. Sanders, |
| nmr spectroscopy in inorganic chemistry: NMR and Chemistry J.W. Akitt, B. E. Mann, 2017-12-21 Keeping mathematics to a minimum, this book introduces nuclear properties, nuclear screening, chemical shift, spin-spin coupling, and relaxation. It is one of the few books that provides the student with the physical background to NMR spectroscopy from the point of view of the whole of the periodic table rather than concentrating on the narrow applications of 1H and 13C NMR spectroscopy. Aids to structure determination, such as decoupling, the nuclear Overhauser effect, INEPT, DEPT, and special editing, and two dimensional NMR spectroscopy are discussed in detail with examples, including the complete assignment of the 1H and 13C NMR spectra of D-amygdain. The authors examine the requirements of a modern spectrometer and the effects of pulses and discuss the effects of dynamic processes as a function of temperature or pressure on NMR spectra. The book concludes with chapters on some of the applications of NMR spectroscopy to medical and non-medical imaging techniques and solid state chemistry of both I = F1/2 and I > F1/2 nuclei. Examples and problems, mainly from the recent inorganic/organometallic chemistry literature support the text throughout. Brief answers to all the problems are provided in the text with full answers at the end of the book. |
| nmr spectroscopy in inorganic chemistry: NMR Spectroscopy in Liquids and Solids Vladimir I. Bakhmutov, 2015-04-10 NMR Spectroscopy in Liquids and Solids provides an introduction of the general concepts behind Nuclear Magnetic Resonance (NMR) and its applications, including how to perform adequate NMR experiments and interpret data collected in liquids and solids to characterize molecule systems in terms of their structure and dynamics.The book is composed of t |
| nmr spectroscopy in inorganic chemistry: Modern NMR Techniques for Chemistry Research A.E. Derome, 2013-10-22 Presents an introduction to modern NMR methods at a level suited to organic and inorganic chemists engaged in the solution of structural and mechanistic problems. The book assumes familiarity only with the simple use of proton and carbon spectra as sources of structural information and describes the advantages of pulse and Fourier transform spectroscopy which form the basis of all modern NMR experiments. Discussion of key experiments is illustrated by numerous examples of the solutions to real problems. The emphasis throughout is on the practical side of NMR and the book will be of great use to chemists engaged in both academic and industrial research who wish to realise the full possibilities of the new wave NMR. |
| nmr spectroscopy in inorganic chemistry: Modern NMR Spectroscopy Jeremy K. M. Sanders, 1993 Nuclear magnetic resonance techniques have advanced dramatically in recent years, and are now more powerful and more versatile than ever before. To exploit these techniques efficiently, the chemist must have both an understanding of their theoretical basis and the ability to interpret the spectra accurately. The new edition of this established workbook develops the latter skill to an advanced level by a combination of worked examples and set problems that cover one- and two-dimensional NMR techniques applied to organic and inorganic systems. Most of the problems are genuine research examples, and this new edition contains eight pages of problems drawn from very recent research work. This second edition is fully compatible with the second edition of Modern NMR Spectroscopy: a guide for chemists, and the two books are thoroughly cross referenced throughout. |
| nmr spectroscopy in inorganic chemistry: NMR, NQR, EPR, and Mössbauer Spectroscopy in Inorganic Chemistry Richard Vernon Parish, 1990 |
| nmr spectroscopy in inorganic chemistry: Organic Structures from 2D NMR Spectra L. D. Field, H. L. Li, A. M. Magill, 2015-06-15 The derivation of structural information from spectroscopic data is now an integral part of organic chemistry courses at all Universities. Over recent years, a number of powerful two-dimensional NMR techniques (e.g. HSQC, HMBC, TOCSY, COSY and NOESY) have been developed and these have vastly expanded the amount of structural information that can be obtained by NMR spectroscopy. Improvements in NMR instrumentation now mean that 2D NMR spectra are routinely (and sometimes automatically) acquired during the identification and characterisation of organic compounds. Organic Structures from 2D NMR Spectra is a carefully chosen set of more than 60 structural problems employing 2D-NMR spectroscopy. The problems are graded to develop and consolidate a student’s understanding of 2D NMR spectroscopy. There are many easy problems at the beginning of the collection, to build confidence and demonstrate the basic principles from which structural information can be extracted using 2D NMR. The accompanying text is very descriptive and focussed on explaining the underlying theory at the most appropriate level to sufficiently tackle the problems. Organic Structures from 2D NMR Spectra Is a graded series of about 60 problems in 2D NMR spectroscopy that assumes a basic knowledge of organic chemistry and a basic knowledge of one-dimensional NMR spectroscopy Incorporates the basic theory behind 2D NMR and those common 2D NMR experiments that have proved most useful in solving structural problems in organic chemistry Focuses on the most common 2D NMR techniques – including COSY, NOESY, HMBC, TOCSY, CH-Correlation and multiplicity-edited C-H Correlation. Incorporates several examples containing the heteronuclei 31P, 15N and 19F Organic Structures from 2D NMR Spectra is a logical follow-on from the highly successful “Organic Structures from Spectra” which is now in its fifth edition. The book will be invaluable for students of Chemistry, Pharmacy, Biochemistry and those taking courses in Organic Chemistry. Also available: Instructors Guide and Solutions Manual to Organic Structures from 2D NMR Spectra |
| nmr spectroscopy in inorganic chemistry: NMR in Organometallic Chemistry Paul S. Pregosin, 2013-07-26 The first and ultimate guide for anyone working in transition organometallic chemistry and related fields, providing the background and practical guidance on how to efficiently work with routine research problems in NMR. The book adopts a problem-solving approach with many examples taken from recent literature to show readers how to interpret the data. Perfect for PhD students, postdocs and other newcomers in organometallic and inorganic chemistry, as well as for organic chemists involved in transition metal catalysis. |
| nmr spectroscopy in inorganic chemistry: Biological NMR Spectroscopy John L. Markley, Stanley J. Opella, 1997-01-30 This book presents a critical assessment of progress on the use of nuclear magnetic resonance spectroscopy to determine the structure of proteins, including brief reviews of the history of the field along with coverage of current clinical and in vivo applications. The book, in honor of Oleg Jardetsky, one of the pioneers of the field, is edited by two of the most highly respected investigators using NMR, and features contributions by most of the leading workers in the field. It will be valued as a landmark publication that presents the state-of-the-art perspectives regarding one of today's most important technologies. |
| nmr spectroscopy in inorganic chemistry: NMR Data Interpretation Explained Neil E. Jacobsen, 2016-10-21 Through numerous examples, the principles of the relationship between chemical structure and the NMR spectrum are developed in a logical, step-by-step fashion Includes examples and exercises based on real NMR data including full 600 MHz one- and two-dimensional datasets of sugars, peptides, steroids and natural products Includes detailed solutions and explanations in the text for the numerous examples and problems and also provides large, very detailed and annotated sets of NMR data for use in understanding the material Describes both simple aspects of solution-state NMR of small molecules as well as more complex topics not usually covered in NMR books such as complex splitting patterns, weak long-range couplings, spreadsheet analysis of strong coupling patterns and resonance structure analysis for prediction of chemical shifts Advanced topics include all of the common two-dimensional experiments (COSY, ROESY, NOESY, TOCSY, HSQC, HMBC) covered strictly from the point of view of data interpretation, along with tips for parameter settings |
| nmr spectroscopy in inorganic chemistry: Applications of NMR Spectroscopy: Volume 2 Atta-ur Rahman, M. Iqbal Choudhary, 2015-12-10 Applications of NMR Spectroscopy, Volume 2, originally published by Bentham and now distributed by Elsevier, presents the latest developments in the field of NMR spectroscopy, including the analysis of plant polyphenols, the role of NMR spectroscopy in neuroradiology, NMR–based sensors, studies on protein and nucleic acid structure and function, and mathematical formations for NMR spectroscopy in structural biology. The fully illustrated chapters contain comprehensive references to the recent literature. The applications presented cover a wide range of the field, such as drug development, medical imaging and diagnostics, food science, mining, petrochemical, process control, materials science, and chemical engineering, making this resource a multi-disciplinary reference with broad applications. The content is ideal for readers who are seeking reviews and updates, as it consolidates scientific articles of a diverse nature into a single volume. Sections are organized based on disciplines, such as food science and medical diagnostics. Each chapter is written by eminent experts in the field. - Consolidates the latest developments in NMR spectroscopy into a single volume - Authored and edited by world-leading experts in spectroscopy - Features comprehensive references to the most recent related literature - More than 65 illustrations aid in the retention of key concepts |
| nmr spectroscopy in inorganic chemistry: NMR in Supramolecular Chemistry Miquel Pons, 1999-03-31 NMR is better suited than any other experimental technique for the characterization of supramolecular systems in solution. The presentations included here can be broadly divided into three classes. The first class illustrates the state of the art in the design of supramolecular systems and includes examples of different classes of supramolecular complexes: catenanes, rotaxanes, hydrogen-bonded rosettes, tubes, capsules, dendrimers, and metal-containing hosts. The second class comprises contributions to NMR methods that can be applied to address the main structural problems that arise in supramolecular chemistry. The third class includes biological supramolecular systems studied by state-of-the-art NMR techniques. |
| nmr spectroscopy in inorganic chemistry: Spectroscopy in Inorganic Chemistry Chintamani Nagesa Ramachandra Rao, John Ralph Ferraro, 1971 |
| nmr spectroscopy in inorganic chemistry: Modelling 1H NMR Spectra of Organic Compounds Raymond J. Abraham, Mehdi Mobli, 2008-11-20 Provides a theoretical introduction to graduate scientists and industrial researchers towards the understanding of the assignment of 1H NMR spectra Discusses, and includes on enclosed CD, one of the best, the fastest and most applicable pieces of NMR prediction software available Allows students of organic chemistry to solve problems on 1H NMR with access to over 500 assigned spectra |
| nmr spectroscopy in inorganic chemistry: Tables of Spectral Data for Structure Determination of Organic Compounds Ernö Pretsch, T. Clerc, J. Seibl, W. Simon, 2013-06-29 Although numerical data are, in principle, universal, the compilations presented in this book are extensively annotated and interleaved with text. This translation of the second German edition has been prepared to facilitate the use of this work, with all its valuable detail, by the large community of English-speaking scientists. Translation has also provided an opportunity to correct and revise the text, and to update the nomenclature. Fortunately, spectroscopic data and their relationship with structure do not change much with time so one can predict that this book will, for a long period of time, continue to be very useful to organic chemists involved in the identification of organic compounds or the elucidation of their structure. Klaus Biemann Cambridge, MA, April 1983 Preface to the First German Edition Making use of the information provided by various spectroscopic tech niques has become a matter of routine for the analytically oriented organic chemist. Those who have graduated recently received extensive training in these techniques as part of the curriculum while their older colleagues learned to use these methods by necessity. One can, therefore, assume that chemists are well versed in the proper choice of the methods suitable for the solution of a particular problem and to translate the experimental data into structural information. |
| nmr spectroscopy in inorganic chemistry: Infrared and Raman Spectra of Inorganic and Coordination Compounds, Part A Kazuo Nakamoto, 2008-12-22 The Sixth Edition of this classic work comprises the most comprehensive and current guide to infrared and Raman spectra of inorganic, organometallic, bioinorganic, and coordination compounds. From fundamental theories of vibrational spectroscopy to applications in a variety of compound types, this has been extensively updated. New topics include the theoretical calculations of vibrational frequencies (DFT method), chemical synthesis by matrix co-condensation reactions, time-resolved Raman spectroscopy, and more. This volume is a core reference for chemists and medical professionals working with infrared or Raman spectroscopies and an excellent textbook for graduate courses. |
| nmr spectroscopy in inorganic chemistry: Solid-State NMR II B. Blümich, 2013-03-09 1. G. Engelhardt, H. Koller, Stuttgart, FRG: 29Si NMR of Inorganic Solids 2. H. Pfeifer, Leizpig, FRG: NMR of Solid Surfaces 3. A. Sebald, Bayreuth, FRG: MAS and CP/MAS NMR of Less Common Spin-1/2 Nuclei 4. C. J{ger, Mainz, FRG: Satellite Transition Spectroscopy of Quadrupolar Nuclei 5. D. Brinkmann, M. Mali, Z}rich, CH: NMR-NQR Studies of High-Temperature Superconductors. |
| nmr spectroscopy in inorganic chemistry: NMR Methods for Characterization of Synthetic and Natural Polymers Rongchun Zhang, Toshikazu Miyoshi, Pingchuan Sun, 2019-07-29 Since the introduction of FT-NMR spectroscopy around five decades ago, NMR has achieved significant advances in hardware and methodologies, accompanied with the enhancement of spectral resolution and signal sensitivity. Rapid developments in the polymers field mean that accurate and quantitative characterization of polymer structures and dynamics is the keystone for precisely regulating and controlling the physical and chemical properties of the polymer. This book specifically focuses on NMR investigation of complex polymers for the polymer community as well as NMR spectroscopists, and will push the development of both fields. It covers the latest advances, for example high field DNP and ultrafast MAS methodologies, and show how these novel NMR methods characterize various synthetic and natural polymers. |
| nmr spectroscopy in inorganic chemistry: Modern NMR Techniques for Synthetic Chemistry Julie Fisher, 2014-10-13 A blend of theory and practical advice, Modern NMR Techniques for Synthetic Chemistry illustrates how NMR spectroscopy can be used to determine the abundance, size, shape, and function of organic molecules. It provides you with a description the NMR technique used (more pictorial than mathematical), indicating the most common pulse sequences, some practical information as appropriate, followed by illustrative examples. This format is followed for each chapter so you can skip the more theoretical details if the practical aspects are what interest you. Following a discussion of basic parameters, the book describes the utility of NMR in detecting and quantifying dynamic processes, with particular emphasis on the usefulness of saturation-transfer (STD) techniques. It details pulsed–field gradient approaches to diffusion measurement, diffusion models, and approaches to ‘inorganic’ nuclei detection, important as many synthetic pathways to new organics involve heavier elements. The text concludes with coverage of applications of NMR to the analysis of complex mixtures, natural products, carbohydrates, and nucleic acids—all areas of activity for researchers working at the chemistry-life sciences interface. The book’s unique format provides some theoretical insight into the NMR technique used, indicating the most common pulse sequences. The book draws upon several NMR methods that are resurging or currently hot in the field and indicates the specific pulse sequence used by various spectrometer manufacturers for each technique. It examines the analysis of complex mixtures, a feature not found in most books on this topic. |
| nmr spectroscopy in inorganic chemistry: Spin States in Biochemistry and Inorganic Chemistry Marcel Swart, Miquel Costas, 2015-09-17 It has long been recognized that metal spin states play a central role in the reactivity of important biomolecules, in industrial catalysis and in spin crossover compounds. As the fields of inorganic chemistry and catalysis move towards the use of cheap, non-toxic first row transition metals, it is essential to understand the important role of spin states in influencing molecular structure, bonding and reactivity. Spin States in Biochemistry and Inorganic Chemistry provides a complete picture on the importance of spin states for reactivity in biochemistry and inorganic chemistry, presenting both theoretical and experimental perspectives. The successes and pitfalls of theoretical methods such as DFT, ligand-field theory and coupled cluster theory are discussed, and these methods are applied in studies throughout the book. Important spectroscopic techniques to determine spin states in transition metal complexes and proteins are explained, and the use of NMR for the analysis of spin densities is described. Topics covered include: DFT and ab initio wavefunction approaches to spin states Experimental techniques for determining spin states Molecular discovery in spin crossover Multiple spin state scenarios in organometallic reactivity and gas phase reactions Transition-metal complexes involving redox non-innocent ligands Polynuclear iron sulfur clusters Molecular magnetism NMR analysis of spin densities This book is a valuable reference for researchers working in bioinorganic and inorganic chemistry, computational chemistry, organometallic chemistry, catalysis, spin-crossover materials, materials science, biophysics and pharmaceutical chemistry. |
| nmr spectroscopy in inorganic chemistry: Multinuclear Solid-State Nuclear Magnetic Resonance of Inorganic Materials Kenneth J.D. MacKenzie, M.E. Smith, 2002-04-26 Techniques of solid state nuclear magnetic resonance (NMR) spectroscopy are constantly being extended to a more diverse range of materials, pressing into service an ever-expanding range of nuclides including some previously considered too intractable to provide usable results. At the same time, new developments in both hardware and software are being introduced and refined. This book covers the most important of these new developments.With sections addressed to non-specialist researchers (providing accessible answers to the most common questions about the theory and practice of NMR asked by novices) as well as a more specialised and up-to-date treatment of the most important areas of inorganic materials research to which NMR has application, this book should be useful to NMR users whatever their level of expertise and whatever inorganic materials they wish to study. |
| nmr spectroscopy in inorganic chemistry: Experimental Approaches of NMR Spectroscopy The Nuclear Magnetic Resonance Society of Japan, 2017-11-23 This book describes the advanced developments in methodology and applications of NMR spectroscopy to life science and materials science. Experts who are leaders in the development of new methods and applications of life and material sciences have contributed an exciting range of topics that cover recent advances in structural determination of biological and material molecules, dynamic aspects of biological and material molecules, and development of novel NMR techniques, including resolution and sensitivity enhancement. First, this book particularly emphasizes the experimental details for new researchers to use NMR spectroscopy and pick up the potentials of NMR spectroscopy. Second, the book is designed for those who are involved in either developing the technique or expanding the NMR application fields by applying them to specific samples. Third, the Nuclear Magnetic Resonance Society of Japan has organized this book not only for NMR members of Japan but also for readers worldwide who are interested in using NMR spectroscopy extensively. |
| nmr spectroscopy in inorganic chemistry: NMR Spectroscopy of Polymers H.N. Cheng, Tetsuo Asakura, Alan English, 2012-04-19 Includes review and papers on the latest advances by acknowledged leaders and active researchers in nuclear magnetic resonance (NMR) spectroscopy |
| nmr spectroscopy in inorganic chemistry: Structure Elucidation by NMR in Organic Chemistry Eberhard Breitmaier, 2002-11-22 This text provides the graduate student with a systematic guide to unravelling structural information from the NMR spectra of unknown synthetic and natural compounds. A brief introduction gives an overview of the basic principles and elementary instrumental methods of NMR. This is followed by instructional strategy and tactical advice on how to translate spectra into meaningful structural information. The book provides the student with 55 sets of spectra of graduated complexity. These are designed to challenge the student's problem-solving abilities by the introduction of new concepts with each group of problems, followed by possible solutions and full explanations. A formula index of solutions is provided at the end of the text. This third edition, following on from the second (a reprint of the first edition with corrections), presents significant new material. Thus, actual methods of two-dimensional NMR such as some inverse techniques of heteronuclear shift correlation, as well as the detection of proton-proton connectivities and nuclear Overhauser effects are included. To demonstrate the applications of these methods, new problems have replaced those of previous editions. |
| nmr spectroscopy in inorganic chemistry: Basic One- and Two-dimensional NMR Spectroscopy Horst Friebolin, 1993 |
| nmr spectroscopy in inorganic chemistry: Spectroscopic Methods in Organic Chemistry Dudley H. Williams, Ian Fleming, 1980 |
| nmr spectroscopy in inorganic chemistry: Spectroscopic Properties of Inorganic and Organometallic Compounds G. Davidson, 1994 Spectroscopic Properties of Inorganic and Organometallic Compounds provides a unique source of information on an important area of chemistry. Divided into sections mainly according to the particular spectroscopic technique used, coverage in each volume includes: NMR (with reference to stereochemistry, dynamic systems, paramagnetic complexes, solid state NMR and Groups 13-18); nuclear quadrupole resonance spectroscopy; vibrational spectroscopy of main group and transition element compounds and coordinated ligands; and electron diffraction. Reflecting the growing volume of published work in this field, researchers will find this Specialist Periodical Report an invaluable source of information on current methods and applications. Specialist Periodical Reports provide systematic and detailed review coverage in major areas of chemical research. Compiled by teams of leading experts in their specialist fields, this series is designed to help the chemistry community keep current with the latest developments in their field. Each volume in the series is published either annually or biennially and is a superb reference point for researchers. www.rsc.org/spr |
Nuclear magnetic resonance - Wikipedia
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Feb 22, 2024 · Nuclear magnetic resonance (NMR) spectroscopy is a physicochemical technique used to obtain structural information about molecules. In this article, we consider how it works, …
Nuclear magnetic resonance - Wikipedia
Nuclear magnetic resonance (NMR) is a physical phenomenon in which nuclei in a strong constant magnetic field are disturbed by a weak oscillating magnetic field (in the near field [1]) …
4.7: NMR Spectroscopy - Chemistry LibreTexts
Aug 28, 2022 · Nuclear magnetic resonance spectroscopy (NMR) is a widely used and powerful method that takes advantage of the magnetic properties of certain nuclei. The basic principle …
NMR Spectroscopy- Definition, Principle, Steps, Parts, Uses
Jan 12, 2022 · What is NMR? Nuclear magnetic resonance spectroscopy, most commonly known as NMR spectroscopy or magnetic resonance spectroscopy (MRS), is a spectroscopic …
How to Interpret NMR Spectroscopy Results: A Beginner's Guide
May 29, 2025 · The NMR spectrum (¹H-NMR and ¹³C-NMR) is a graphical representation of nuclear resonance signals, with chemical shift (ppm) on the x-axis indicating the electronic …
NMR Spectroscopy - Michigan State University
Over the past fifty years nuclear magnetic resonance spectroscopy, commonly referred to as nmr, has become the preeminent technique for determining the structure of organic compounds. Of …
Nuclear magnetic resonance (NMR) | Britannica
May 15, 2025 · Nuclear magnetic resonance (NMR), selective absorption of very high-frequency radio waves by certain atomic nuclei that are subjected to an appropriately strong stationary …
Nuclear magnetic resonance (NMR) spectroscopy - RSC Education
Discover how nuclear magnetic resonance (NMR) spectroscopy works, with this series of topics breaking down the fundamental theory. Covering the electronic environment of atoms right up …
NMR Basics | Nuclear Magnetic Resonance Spectroscopy Facility ...
Bloch and Purcell were jointly awarded the Nobel Prize in Physics in 1952 for their discovery of Nuclear Magnetic Resonance Spectroscopy. The NMR phenomenon relies on the interaction …
Understanding NMR Spectroscopy: Principles and Mechanisms
Apr 29, 2025 · Explore the fundamental principles and mechanisms of NMR spectroscopy, including key concepts like chemical shifts and spin-spin coupling. NMR spectroscopy is a vital …
NMR Spectroscopy Principles, Interpreting an NMR Spectrum …
Feb 22, 2024 · Nuclear magnetic resonance (NMR) spectroscopy is a physicochemical technique used to obtain structural information about molecules. In this article, we consider how it works, …
